THE LEWIS BONDING MODEL AND BEYOND
报告人:Professor Gernot Frenking
报告时间:2016年12月15日(星期四)上午9:00
报告地点:万博体育bet丁家桥校区科技创新大楼C501
报告摘要:The lecture discusses fundamental questions of chemical bonding in the light of the Lewis electron-pair model which was introduced 100 years ago [1]. Topics include the electronic structure of molecules with unusual bonds [2] and the differences of chemical bonding between atoms of the first octal row and heavier homologues [3]. It is shown that the complementary model of electron-sharing bonds A-B and dative bonds A→B is very useful to explain molecular structures and to predict novel compounds [4].
参考资料:
[1] a) G.N. Lewis,J. Am.Chem. Soc.1916,38, 762. b) A. Krapp, F. M. Bickelhaupt, G. Frenking,Chem. Eur. J.2006,12, 9196.
[2] a) G. Frenking, R. Tonner, S. Klein, N. Takagi, T. Shimizu, A. Krapp, K. K. Pandey, P. Parameswaran,Chem. Soc. Rev.2014,43,5106. b) J. Jin, G. Wang, M. Zhou, D. M. Andrada, M. Hermann, G. Frenking,Angew. Chem. Int. Ed.2016,55,2078. c) K. C. Mondal, S. Roy, B. Dittrich, D. M. Andrada, G. Frenking, H. W. Roesky,Angew. Chem. Int. Ed.2016,55,3158. d) Z.-H. Cui, W-S. Yang, L. Zhao, Y.-H. Ding, G. Frenking,Angew.Chem. Int. Ed.,2016,55,7841. e) C. Mohapatra, S. Kundu, A. N. Paesch, R. Herbst-Irmer, D. Stalke, D. M. Andrada, G. Frenking, H. W. Roesky,J. Am.Chem. Soc.2016,138, 10429.
[3] a) P. Jerabek, G. Frenking,Theoret. Chem. Acc.2014,133, 1447. b) G. Frenking, in'The Chemical Bond. Chemical Bonding Across the Periodic Table’, p. 25-48, G. Frenking and S. Shaik (Eds), Wiley-VCH, Weinheim, 2014. c) M. Lein, A. Krapp, G. FrenkingJ. Am.Chem. Soc.2005,127, 6290.
[4] a) G. Frenking,Angew. Chem. Int. Ed.2014,53, 6040. b) M. Hermann, G. Frenking,Structure and Bonding2016,169, 131. c) G. Frenking, M. Hermann, D.M. Andrada, N. Holzmann,Chem. Soc.Rev.2016,45, 1129.
个人简历:
1969-1973 |
德国亚琛工业大学,化学专业 |
1974-1976 |
日本京都Kenichi Fukui教授课题组,硕士 |
1976-1979 |
德国柏林工业大学,博士 |
1979-1984 |
德国柏林工业大学,任教 |
1984-1985 |
美国加州大学伯利克分校,访问科学家 |
1985-1989 |
美国加州斯坦福国际研究所,科学家 |
1990-1998 |
德国马堡大学计算化学专业,副教授 |
1998-2014 |
德国马堡大学理论化学专业,教授 |
2014年至今 |
德国马堡大学,名誉教授 |
2015年至今 |
西班牙圣塞瓦斯蒂安市DIPC,客座教授 |
获奖荣誉:
v日本教育部奖学金 |
1973 |
v西班牙皇家化学学会Elhuyar-Goldschmidt奖 |
2007 |
v英国皇家化学学会成员 |
2008 |
v世界理论和计算机化学协会薛定谔勋章 |
2009 |
v德国马堡大学Hans-HellmannProfessor荣誉 |
2012 |