赵恺教授

Email: ias_kzhao@njtech.edu.cn

个人简介：

2022-至今万博体育bet,化学与分子工程学院,教授

2017-2022万博体育bet,先进化学制造研究院,副教授

2015-2016新加坡南洋理工大学,化学与生物化学系,博士后(导师: Teck-Peng Loh教授)

2014-2015新加坡南洋理工大学,化学与生物化学系,研究助理

2010-2014新加坡南洋理工大学,化学与生物化学系,博士(导师: Teck-Peng Loh教授)

2007-2010苏州大学,材料与化学化工学部,硕士(导师:纪顺俊教授)

2003-2007苏州大学,材料与化学化工学部,学士

学术成绩：

主要从事烯酰胺类化合物的区域及立体选择性碳-氢官能化转化，廉价过渡金属催化的碳-碳成键反应，光催化的环境友好型自由基反应等领域的研究工作。自2017年9月入职万博体育bet 以来，已累计发表高质量SCI论文(影响因子>5.0) 13篇，影响因子总和突破140;累计被引180余次。其中以第一作者身份在Chemical Society Reviews (影响因子: 54.564)发表封面论文1篇(Chem. Soc. Rev.2017,46, 586.)；以通讯作者身份在Chemical Science (影响因子: 9.825)上发表论文1篇(Chem. Sci.2019,10, 8792.)并被知名公众号X-Mol重点评述；在Green Chemistry (影响因子: 11.034)上发表论文3篇(Green Chem.2022,24, 4004;Green Chem.2022,24, 6524;Green. Chem.2020,22, 5497.)；在Organic Letters (影响因子：6.555)上发表论文4篇(Org. Lett.2020,22, 9029;Org. Lett.2019,21, 5101;Org. Lett.2019,21, 6155;Org. Lett.2019,21, 8395.)；在Organic Chemistry Frontiers (影响因子: 5.456)上发表论文3篇(Org. Chem. Front.2022,9, 6540;Org. Chem. Front.2021,8, 4086;Org. Chem. Front.2019,6, 94.)，相继入选该杂志热点论文，并被公众号Frontiers Journals重点评述；在Advanced Synthesis & Catalysis (影响因子: 5.837)上发表论文1篇(Adv. Synth. Catal.2019,361, 3593.)。

所获奖励及荣誉：

1.江苏省双创博士(2018)

2.第五届江苏省科协青年会员(化学化工领域)创新创业大赛一等奖(2020)

3.万博体育bet 第十二届“明发杯”青年教师授课竞赛特等奖(2022)

4.万博体育bet 第十一届“明发杯”青年教师授课竞赛一等奖(2020)

5.万博体育bet“明发杯”教学创新大赛一等奖(2021)

6.万博体育bet“以誓立廉，以行践廉”誓词征集最佳创意作品奖(2022)

7.万博体育bet 微课教学比赛二等奖(2022)

8.万博体育bet 实验创新大赛三等奖(2022)

代表性论文：

1.Guan, T.; Guo, J.-Y.; Zhang, Q.-H.; Xu, X.-W.; Yu, X.-Y.; Zhang, Y.;Zhao, K.^*Photoredox-Catalyzed Regio- & Stereoselective C(sp²)–H Cyanoalkylation of Enamides with Cycloketone OximesviaSelective C–C Bond Cleavage/Radical Addition Cascade.Green Chem.2022,24, 6524−6530. (SCI一区；IF: 11.034)

2.Tao, J.-Y.; Wang, Y.-X.; Zhang, Q.-H.; Ni, K.; Zhu, T.-H.;Zhao, K.^*Transition-Metal-Free Regioselective and Stereoselective C(sp²)-C(sp³) Coupling of Enamides with Ethers or AlkanesviaPhotoredox-Catalyzed Cross-Dehydrogenative Coupling Reactions.Green Chem.2022,24, 4004−4011.(SCI一区；IF: 11.034)

3.Zhao, K.^*; Zhang, X.-C.; Tao, J-Y.; Wu, X.-D.; Wu, J.-X.; Li, W.-M.; Zhu, T.-H.^*; Loh, T.-P.^*Regio- and Stereoselective C(sp²)-H Acylation of Enamides with AldehydesviaTransition- Metal Free Photoredox Catalysis.Green Chem.2020,22, 5497−5503.(SCI一区；IF: 10.182)

4.Zhao, K.;Shen, L.; Shen, Z.-L.^*; Loh, T.-P.^*TransitionMetal-CatalyzedCross-Coupling Reactions Using Organoindium Reagents,Chem. Soc. Rev.2017,46, 586−602.(SCI一区；IF: 54.564)

5.Guo, J.-Y.; Zhang, Z.-Y.; Guan, T.; Mao, L.-W.; Ban, Q.;Zhao, K.^*; Loh, T.-P.^*Photoredox-Catalyzed Stereoselective Alkylation of Enamides withN-Hydroxyphthalimide EstersviaDecarboxylative Cross-Coupling Reactions.Chem. Sci.2019,10, 8792−8798.(SCI一区；IF: 9.825)

6.Zhao, K.^*; Zhang, Z.-Y.; Cui, X.-L.; Wang, Y.-X.; Wu, X.-D.; Li, W.-M.; Wu, J.-X.; Zhao, L.-L.^*; Guo, J.-Y.^*; Loh, T.-P.^*Visible-Light-Induced Regio- and Stereoselective C(sp²)−H Trifluoroethylation of Enamides with 2,2,2-Trifluoroethyl Iodide.Org. Lett.2020,22, 9029−9035. (SCI一区；IF: 6.091)

7.Guo, J.-Y.; Guan, T.; Tao, J.-Y.;Zhao, K.^*; Loh, T.-P.^*Stereoselective C(sp²)-H Alkylation of Enamides with Unactivated Aliphatic Carboxylic AcidsviaDecarboxylative Cross-Coupling Reactions,Org. Lett.2019,21, 8395−8399.(SCI一区；IF: 6.555)

8.Zhu, T.-H.; Zhang, Z.-Y.; Tao, J.-Y.;Zhao, K.^*; Loh, T.-P.^*Regioselective andStereoselective Difluoromethylation of Enamides with Difluoromethyltriphenyl-phosphonium BromideviaPhotoredox Catalysis,Org. Lett.2019,21, 6155−6159. (SCI一区；IF: 6.555)

9.Zhang, Y.-H.; Zhang, W.-W.; Zhang, Z.-Y.;Zhao, K.^*;Loh, T.-P.^*Manganese-Catalyzed Ring-Opening Coupling Reactions of Cyclopropanols with Enones,Org. Lett.2019,21, 5101−5105. (SCI一区；IF: 6.555)

10.Tao, J.-Y.; Zhang, Q.-H.; Zhu, T.-H.; Xu, X.-W.; Ni, K.; Zhao, Q.; Qin, Z.-B.; Zhang, Y.; Zhao, L.;Zhao, K.^*Visible-Light-Initiated Regio and Stereoselective C(sp²)–H Phosphorylation of Enamides under Transition-Metal-Free Conditions.Org. Chem. Front.2022,9, 6540−6546.(SCI一区；IF: 5.456)

11.Zhao, K.^*; Guo, J.-Y.^*; Guan, T.; Wang, Y.-X.; Tao, J.-Y.; Zhang, Y.; Zhang, Q.-H.; Ni, K.; Loh, T.-P.^*Photoinitiated Stereoselective Direct C(sp²)-H Perfluoroalkylation and Difluoroacetylation of Enamides.Org. Chem. Front.2021,8, 4086−4094. (SCI一区；IF: 5.456)

12.Zhu, T.-H.; Zhang, X.-C.;Zhao, K.^*; Loh, T.-P.^*Cu(OTf)₂-Mediated C(sp²)-H Arylsulfonylation of Enamidesviathe Insertion of Sulfur Dioxide,Org. Chem. Front.2019,6, 94−98. (SCI一区；IF: 5.076)

13.Zhu, T.-H.; Zhang, X.-C.;Zhao, K.^*, Loh, T.-P.^*Direct C(sp²)−H Arylsulfonylation of Enamidesviairidium(III)-Catalyzed Insertion of Sulfur Dioxide with Aryldiazonium Tetrafluoroborates.Adv. Syn. & Catal.2019,361, 3593−3598. (SCI二区；IF: 5.837)

14.Zhao, K.;Loh, T.-P.^*, Asymmetric Conjugate Addition of Grignard Reagents to 3-silyl Unsaturated Esters for the Facile Preparation of Enantioenrichedβ-Silylcarbonyl Compounds and Allylic Silanes,Chem. Eur. J.2014,20, 16764−16772.

15.Zhao, K.;Zhu, S.-L.; Shi, D.-Q.; Xu, X.-P.^*; Ji, S.-J.^*,Regioselective Synthesis of Highly Functionalized 3-Spiropyrrolidine/pyrrolizidine Oxindoles and AcenaphthenonesviaOne-Pot Four-Component [3+2] Cycloaddition,Synthesis2010, 1793−1803.

16.Zhao, K.; Xu, X.-P.; Zhu, S.-L.; Shi, D.-Q.; Zhang, Y.; Ji, S.-J.^*, Facile and Efficient Synthesis of a New Class of Indole-Substituted Pyridine DerivativesviaOne-Pot Multicomponent Reactions,Synthesis2009, 2697−2708.