Graphene-based hydrogel with embedded gold nanoparticles as a recyclable catalyst for the degradation of 4-nitrophenol

Li Zhang,^aLei Sun,^a,cTing Su,^aTingting Chen,^aLianhong Hu,^aFei He,^c,*Hui Xu,^a,b,**

^aInstitute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

^bState Key Laboratory of Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China

^cNanjing Institute of Environmental Sciences, Ministry of Ecology and Environment of the People’s Republic of China, Nanjing 210042, China

Abstract:Hydrogels have been utilized as a sort of scaffold in catalytic field since they can offer good accommodation for noble metal nanoparticles (NPs) to the preparation of recyclable catalysts. In this work, the poly(4-vinylpyridine) (P4VP) grafted graphene oxide (GO) was firstly synthesized through surface-initiated atom transfer radical polymerization (SI−ATRP). Then, a tough and self-healable composite hydrogel was fabricated by integration of the P4VP-grafted GO into poly(acrylic acid) (PAA) matrix through hierarchically hydrogen-bonding interactions and simultaneous in-situ growth of gold nanoparticles (AuNPs) in the hydrogel scaffold. The as-prepared AuNPs@GO-g-P4VP/PAA composite hydrogel possesses improved mechanical strength and integrity, and exhibits higher catalytic activity in the reductive degradation of 4-nitrophenol into 4-aminophenol than other reported AuNPs-loaded hydrogel catalysts. In addition, the self-healing composite hydrogel catalyst shows ease of separation as well as good reusability without obvious loss of catalytic activity. This work provides an attractive method for the synthesis of robust functional nanoparticle-embedded composite hydrogel for application in various fields.

Colloids and Surfaces A: Physicochemical and Engineering Aspects640 (2022) 128410. (2022年影响因子: 5.518)

论文链接：https://doi.org/10.1016/j.colsurfa.2022.128410